Robinson Annulation Robinson Annulation is an useful organic reaction. This reaction is named after a British chemist Sir Robert Robinson. The term ’annulation ’stands for ’building a ring ’. In this reaction‚ the formation of α‚ β-unsaturated cyclic ketones from methl vinyl ketones and aldehyde or ketones takes place. Actually this reaction is a combination of two reactions. One is ’Michael Addition ’ and the other is ’Aldol Condensation ’. Robinson Annulation Mechanism In the first step
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2-Hexanone Hexanoic Anhydride Hexonic Acid Hexanoamide Hexanal Methyl Hexanode Hexanal Chloride Hex-3-en-2-one Spartan Vibrational frequencies: Compound Frequencies (in ) 2-Hexanone 1934 Hexanoic Anhydride 1946 Hexonic Acid 1964 Hexanoamide 1895 Hexanal 1918 Methyl Hexanode 1940 Hexanal Chloride 1968 Hex-3-en-2-one 1916 Frequencies from the IR spectrophotometer: Compound Frequencies (in ) 2-Hexanone 1716
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NAME OF COURSE COURSE CODE CREDIT TOTAL STUDENT LEARNING HOURS PREREQUISITE LEARNING OUTCOME : : : : Organic Chemistry I CHM 3201 4 (3+1) 160 hours per semester : : None At the end of the course‚ students will be able to: 1. Define and explain the basic concepts in organic chemistry such as electronegativity‚ orbital hybridization‚ nomenclature‚ resonance and isomerism‚ as well as organic reactions mechanisms (C4‚ CTPS) 2. to conduct experiments that demonstrate the characteristic reactions
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THEORY: The Diels-Alder cycloaddition reaction was discovered by Otto Diels and Kurt Alder and is very useful in the synthesis of polycyclic compounds. The Diels-Alder reaction can be described as: [4+2] cycloaddition- a diene with 4 π electrons + 2π electrons from the dienophile; a pericyclic concerted reaction- meaning the reaction occurs in a single step (no intermediates) and involves a cyclic redistribution of bonding electrons. In order for a Diels-Alder reaction to take place
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Preparing nitriles from carbonyl compounds is useful in reactions because nitriles are versatile functional groups1. Not only are they versatile functional groups but they serve as precursors in several transformations. The cyano-group is found in many bioactive molecules and plays a role in hydrogen bonding to certain biological receptors.4 Nitriles are carboxylic acid derivatives because they can easily be converted to carboxylic acid under either basic or acidic conditions. Piperonal is an aromatic
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4-chlorophenol to catalyze polymerization reactions2 (By way of the Bunz Adimet process). The metal-carbon bonding in these transition metal complexes often have localized metal to carbon σ-bonding‚ and a degree of π-back bonding‚ which is well observed in carbonyl containing species. π-back bonding occurs when empty π* (anti bonding) orbitals accepts electrons from the metal center’s d-orbitals. Back bonding allows metals like Mo to exist in a wide range of oxidation states‚ as it allows the metal to distribute
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Laboratory #6 Qualitative Tests for Carbonyls: Aldehydes vs. Ketones Introduction Various chemical tests identifying ketones and aldehydes are used in this experiment in order to identify an unknown carbonyl compound. The tests used are: 2‚4-dinitrophenylhydrazone test‚ Tollen’s Test‚ Benedict’s Test‚ Chromic Acid Test‚ aka Bordwell-Wellman Test‚ Schiff’s Test‚ and Iodoform Test. These classification tests provide results based on color change or formation of precipitation‚ which is then used
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SYNTHESIS OF TRANS-9-(2-PHENYLETHENYL) ANTHRACENE (A WITTIG REACTION) Introduction: The purpose of this experiment is to convert carbonyl compounds to alkenes using Wittig reaction. In this case we will be synthesizing Trans-9-(2-phenylethenyl) anthracene from benzyltriphenylphosphonium chloride and 9-anthraldehyde. We will also aim to obtaining a high percent yield and purity for the synthesis of Trans-9-(2-phenylethenyl) anthracene. The mechanism for this reaction goes thus:
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School of Chemistry @ Pietermaritzburg University of KwaZulu Natal Chemistry 310 Substitution reaction of Molybdenum Hexacarbonyl: the use of infrared spectroscopy as a structural tool in metal carbonyl chemistry. Abstract The synthesis of isomer A and B of [Mo(CO)4(PPh3)2] were prepared from molybdenum hexacarbonyl‚ sodium borohydride and triphenylphosphine with a % yield of 79% and 8.5% respectively. Two isomer was identified using IR spectra and from isomer A four C≡O stretching
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sometimes known as the carbonyl process is a technique created by Ludwig Mond in 1890 to extract and purify nickel. The process was used commercially before the end of the 19th century. It is done by converting nickel oxides (nickel combined with oxygen) into pure nickel. Spheres of Nickel made by Mond’s Process. This process makes use of the fact that carbon monoxide complexes with nickel readily and reversibly to give nickel carbonyl. No other element forms a carbonyl compound under the
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